Three-State Complex Valued Spins Coupled to Binary Branched Polymers in Two-Dimensional Quantum Gravity

A model of complex spins (corresponding to a non-minimal model in the language of CFT) coupled to the binary branched polymer sector of quantum gravity is considered. We show that this leads to new behaviour.Comment: 3 pages, Latex2e, 2 eps figures, uses espcrc2 and epsf. Contribution to LATTICE 97, to appear in the Proceeding

Branched polymers, complex spins and the freezing transition

We show that by coupling complex three-state systems to branched-polymer like ensembles we can obtain models with gamma-string different from one half. It is also possible to study the interpolation between dynamical and crystalline graphs for these models; we find that only when geometry fluctuations are completely forbidden is there a crystalline phase.Comment: 14 pages plain LateX2e, 4 eps figures included using eps

The footloose entrepreneur model with a finite number of equidistant regions

We study the Footloose Entrepreneur model with a finite number of equidistant regions, focusing on the analysis of stability of agglomeration, total dispersion, and boundary dispersion. As the number of regions increases, there is more tendency for agglomeration and less tendency for dispersion. As it tends to infinity, agglomeration always becomes stable while dispersion always becomes unstable. These results are robust to any composition of the global workforce and its dependence on the number of regions. Numerical evidence suggests that boundary dispersion is never stable. We introduce exogenous regional heterogeneity and obtain a general condition for stability of agglomeration.info:eu-repo/semantics/acceptedVersio

Agglomeration patterns in a multi-regional economy without income effects

We study the long-run spatial distribution of industry using a multi-region core–periphery model with quasi-linear log utility Pflüger (Reg Sci Urban Econ 34:565–573, 2004). We show that a distribution in which industry is evenly dispersed among some of the regions, while the other regions have no industry, cannot be stable. A spatial distribution where industry is evenly distributed among all regions except one can be stable, but only if that region is significantly more industrialized than the other regions. When trade costs decrease, the type of transition from dispersion to agglomeration depends on the fraction of workers that are mobile. If this fraction is low, the transition from dispersion to agglomeration is catastrophic once dispersion becomes unstable. If it is high, there is a discontinuous jump to partial agglomeration in one region and then a smooth transition until full agglomeration. Finally, we find that mobile workers benefit from more agglomerated spatial distributions, whereas immobile workers prefer more dispersed distributions. The economy as a whole shows a tendency towards overagglomeration for intermediate levels of trade costs.info:eu-repo/semantics/acceptedVersio

Economic geography meets hotelling: a home-sweet-home effect

We propose a 2-region core-periphery model where all agents are inter-regionally mobile and have Hotelling-type heterogeneous preferences for location. The utility penalty from residing in a location that is not the preferred one generates the only dispersive force of the model: the home-sweet-home effect. Different distributions of preferences for location induce different spatial distributions in the long-run depending on the short-run general equilibrium economic geography model that is considered. We study the effect of two of those: the linear and the logit home-sweet-home effects.info:eu-repo/semantics/publishedVersio

Reductive decarboxylation of bicyclic prolinic systems: a new approach to the enantioselective synthesis of the Geissman-Waiss lactone. X-ray structure determination of a key lactone intermediate

Two concise and enantioselective syntheses of the necine base precursors (1R,5R)-N-Cbz and N-Boc-2-oxa-6-azabicyclo[3.3.0]octan-3-ones (Geissman-Waiss lactones) were carried out from two enantiomerically pure endocyclic five-membered enecarbamates with overall yields of 23% and 26%, respectively. The synthetic strategy made use of a highly effective and stereoselective [2+2]cycloaddition of enantiomerically pure endocyclic enecarbamates with dichloroketene, as well as an efficient decarboxylation step of a bicyclic alpha-amino acid employing Boger's acyl selenide protocol employing tributyltin hydride. Interesting aspects concerning the regiochemical outcome of Baeyer-Villiger oxidations of bicyclic cyclobutanones are also reported, in which the usual stereoelectronic bias of Baeyer-Villiger oxidation seems to be counterbalanced by steric effects on the putative Criegee intermediate.Duas sínteses do conhecido precursor de bases necínicas, (1R,5R)-N-Cbz e N-Boc 2-oxa-6-azabiciclo[3.3.0]octan-3-onas (lactonas de Geissman-Waiss) foram realizadas com rendimentos globais de 23% e 26%, em seis e cinco etapas respectivamente, a partir de enecarbamatos endocíclicos de cinco membros enantiomericamente puros. A estratégia sintética adotada está fundamentada em uma reação de cicloadição [2+2] eficiente e altamente estereosseletiva de enecarbamatos de cinco membros com diclorocetenos, assim como em uma eficaz descarboxilação de alfa-amino ácidos bicíclicos pelo método de Boger, que utiliza a redução de selenetos de acila por hidretos de estanho. Aspectos relativos a regiosseletividade da reação de oxidação de azabiciclo ciclobutanonas pelo método de Baeyer-Villiger são também descritos, com destaque para um potencial controle regioquímico advindo de aspectos estéreos em contraposição a aspectos estereoeletrônicos.2738Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Vineyard Gap Detection by Convolutional Neural Networks Fed by Multi-Spectral Images

Funding Information: This research was partially funded by Fundação para a Ciência e a Tecnologia under Projects UIDB/00066/2020, UIDB/04111/2020, foRESTER PCIF/SSI/0102/2017, and IF/00325/2015; Instituto Lusófono de Investigação e Desenvolvimento (ILIND) under Project COFAC/ILIND/COPELABS/1/2020; Project “(Link4S)ustainability—A new generation connectivity system for creation and integration of networks of objects for new sustainability paradigms [POCI-01-0247-FEDER-046122 | LISBOA-01-0247-FEDER-046122]” is financed by the Operational Competitiveness and Internationalization Programmes COMPETE 2020 and LISBOA 2020, under the PORTUGAL 2020 Partnership Agreement, and through the European Structural and Investment Funds in the FEDER component; and also IEoT: Intelligent Edge of Things under under Project LISBOA-01-0247-FEDER-069537. Publisher Copyright: © 2022 by the authors.This paper focuses on the gaps that occur inside plantations; these gaps, although not having anything growing in them, still happen to be watered. This action ends up wasting tons of liters of water every year, which translates into financial and environmental losses. To avoid these losses, we suggest early detection. To this end, we analyzed the different available neural networks available with multispectral images. This entailed training each regional and regression-based network five times with five different datasets. Networks based on two possible solutions were chosen: unmanned aerial vehicle (UAV) depletion or post-processing with external software. The results show that the best network for UAV depletion is the Tiny-YOLO (You Only Look Once) version 4-type network, and the best starting weights for Mask-RCNN were from the Tiny-YOLO network version. Although no mean average precision (mAP) of over 70% was achieved, the final trained networks managed to detect mostly gaps, including low-vegetation areas and very small gaps, which had a tendency to be overlooked during the labeling stage.publishersversionpublishe

Piezoelectric polymers as biomaterials for tissue engineering applications

Tissue engineering often rely on scaffolds for supporting cell differentiation and growth. Novel paradigms for tissue engineering include the need of active or smart scaffolds in order to properly regenerate specific tissues. In particular, as electrical and electromechanical clues are among the most relevant ones in determining tissue functionality in tissues such as muscle and bone, among others, electroactive materials and, in particular, piezoelectric ones, show strong potential for novel tissue engineering strategies, in particular taking also into account the existence of these phenomena within some specific tissues, indicating their requirement also during tissue regeneration. This referee reports on piezoelectric materials used for tissue engineering applications. The most used materials for tissue engineering strategies are reported together with the main achievements, challenges and future needs for research and actual therapies. This review provides thus a compilation of the most relevant results and strategies and a start point for novel research pathways in the most relevant and challenging open questions.This work was supported by FEDER through the COMPETE Program and by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Project PEST-C/FIS/UI607/2013 and by the project Matepro – Optimizing Materials and Processes”, ref. NORTE-07-0124-FEDER-000037”, co-funded by the “Programa Operacional Regional do Norte” (ON.2 – O Novo Norte), under the “Quadro de Referência Estratégico Nacional” (QREN), through the “Fundo Europeu de Desenvolvimento Regional” (FEDER). CR, VS and DMC would like to acknowledge the FCT for the SFRH/BPD/90870/2012, SFRH/BD/64901/2009 and SFRH/BD/82411/2011 grants respectively

Development of sandwich panels for multi-functional strengthening of RC buildings: characterization of constituent materials and shear interaction of panel assemblies

This paper presents an experimental and numerical study aiming at the development of a sustainable and multifunctional composite sandwich panel for the rehabilitation of reinforced concrete (RC) buildings from the 1960s to the mid-1980s. The sandwich panel, which was designed for the structural, thermal and acoustic refurbishment of building facades, comprises three main components: (i) thin outer layers of Recycled Steel Fibre Reinforced micro–Concrete (RSFRC) that fulfil the strength, ductility and durability requirements of the panel; (ii) a lightweight core made of polystyrene that provides thermal insulation; and (iii) internally distributed glass fibre reinforced polymer (GFRP) connectors that join the different layers of the panel, providing an adequate structural behaviour to the composite system. The mechanical characterization tests highlighted the viability of using RSFRC for the production of structural sandwich facade panels, as relatively high post-cracking tensile capacity was obtained for thin RSFRC layers. Pushout and pullout tests were carried out on intermediate-scale specimens representative of the sandwich panel solution for assessing the overall composite behaviour of the sandwich panels and analysing the influence of the type of core insulation layer (expanded/extruded polystyrene cores, with different surface finishing), of the anchoring conditions (25 and 35 mm of embedment depth) and diameter of the GFRP connectors (8 and 12 mm). These tests showed that the structural GFRP connectors with diameters of 8 and 12 mm are able to ensure shear load transfer between RSFRC layers, exhibiting better composite behaviour when combined with anchorage depths of 25 and 35 mm, respectively. The numerical part of this study aimed at modelling the failure mechanisms observed at the interface between RSFRC and polystyrene, showing good agreement between experimental and numerical results, with important conclusions being drawn regarding cohesion and friction angle between these materials.The first author wishes to acknowledge the financial support provided by the Portuguese Foundation for Science and Technology (FCT) and the Eco-Construction and Rehabilitation (EcoCoRe) Doctoral Program through the research grant PD/BD/52657/2014. The second author acknowledges the support provided by the project ICoSyTec, POCI-01-0145-FEDER-027990, financed by the FCT (Portuguese Foundation for Science and Technology) and co-funded by FEDER through Operational Competitiveness and Internationalization Programme (POCI)